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It is expected that the analysis of the evaporation process for multicomponent fuels such as actual fuels like gasoline and diesel gas oil could be performed to assess more accurately the mixture preparation field inside the cylinder of D.I.S.I engines and diesel engines. In this paper, we suggested the importance of this multicomponent fuel consideration relating to the mixture formation and combustion characteristics from the basis of their own fuel physical and chemical properties. Then, we introduce a treatment for the phase change of a multicomponent solution through the formation of two-phase regions with the basis of chemical-thermodymical liquid-vapor equilibrium. Next, we analyze the distillation properties of a multicomponent fuel as well as the evaporation process of a multicomponent single droplet by use of the chemical-thermodymical analysis.

This paper presents the analysis of atomization and vaporization processes in a flash boiling spray based on experimental results obtained from injection systems in the suction manifold of a gasoline engine. Two kinds of liquid fuel, n-Pentane and n-Hexane, were injected into quiescent atmosphere at room-temperature and low-pressure through a pintle type injector with electronic control. The spray characteristics of both fuels below various atmospheric pressures were investigated in detail by taking photography. Then, in the region of flash boiling, where the back pressure was below the saturated vapor pressure of fuel, the bubble nucleation process due to the flash boiling was modelled by both the measurement results of bubble and the nucleation rate equation using the degree of superheat of the liquid fuel.

The experiment-based droplet impinging breakup model was applied to a fan shaped spray and the impinging behavior was analyzed quantitatively. Evaluation of the quantitative results with validation tests verified the following. The model enables prediction of fan shaped spray thickness after impingement caused by the breakup of fuel droplets, which could not be represented with the Wall-Jet model, widely used at present. Fuel film movement on a wall is negligible when the injection pressure of the fan shaped spray is high and the spray travelling length is not too short. The proposed heat transfer coefficient between fuel film and the wall is too small to represent the vaporizing rate of the fuel film.

Auto-ignition and combustion processes of dual-component fuel spray were numerically studied. A source code of SUPERTRAPP (developed by NIST), which is capable of predicting thermodynamic and transportation properties of pure fluids and fluid mixtures containing up to 20 components, was incorporated into KIVA3V to provide physical fuel properties and vapor-liquid equilibrium calculations. Low temperature oxidation reaction, which is of importance in ignition process of hydrocarbon fuels, as well as negative temperature coefficient behavior was taken into account using the multistep kinetics ignition prediction based on Shell model, while a global single-step mechanism was employed to account for high temperature oxidation reaction. Computational results with the present multi-component fuel model were validated by comparing with experimental data of spray combustion obtained in a constant volume vessel.

In previous multi-dimensional modeling on spray dynamics and vapor formation, single component fuel with pure substance has been analyzed to assess the mixture formation. Then it should be expected that the evaporation process could be performed for the multicomponent fuel such as actual Gasoline and Diesel gas oil. In this study, vapor-liquid equilibrium prediction was conducted for multicomponent fuels such as 3 and 10 components mixed solution with ideal solution analysis and non-ideal solution analysis. And the computation of distillation characteristics was conducted for the steady state fuel condition fuel condition to understand the evaporation process. As a result, calculated distillation characteristics are consistent well with experiment results. And the evaporation process of a multicomponent droplet in the combustion chamber has been calculated with the variation of ambient pressure and temperature.

Flash-boiling occurs when a fuel is injected to a combustion chamber where the ambient pressure is lower than the saturation pressure of the fuel. It has been known that flashing is a favorable mechanism for atomizing liquid fuels. On the other hand, alternative fuels, such as gaseous fuels and oxygenated fuels, are used to achieve low exhaust emissions in recent years. In general, most of these alternative fuels have high volatility and flash-boiling takes place easily in fuel spray, when they are injected into the combustion chamber of an internal combustion engine under high pressure. In addition, fuel design concept the multicomponent fuel with high and low volatility fuels has been proposed in the previous study in order to control the spray and combustion processes in internal combustion engine. It is found that the multicomponent fuel produce flash-boiling with an increase in the initial fuel temperature.

A transient gas jet and its flame are the most fundamental phenomena of a transient spray and its flame breaking out in a CI engine and an SI engine with the direct injection system. In the case of CNG and LNG engines, the fuel itself is just gaseous state. The 2-LIF technique was applied to the transient gas jet to obtain the mixing process between the surroundings and it, and the simultaneous application of LII and LIS techniques were applied to the transient gas jet flame to obtain the soot formation process.

In an SI engine with direct injection of gasoline (DGI), many small droplets disperse in premixed gas in the cylinder. In a CI engine, diesel spray is injected a cylinder, thus, the situation at the spray periphery is almost the same as that of DGI SI engine. From the standpoint it is useful for understanding the combustion phenomena in both engines to experiment the combined combustion of premixed gas where many small droplets exist. This paper describes this kind of combustion and it seems to be able to apply the results to the simulation of combustion in these engines.

In SI engines with port injection system, the injected fuel spray adheres surely on the port wall and the inlet valve, consequently, the spray-wall interaction process leads to the generation of unburned hydrocarbons and uncontrollable mixture formation. This paper deals with the fuel mixture preparation process including basic research on characteristics of the wall-wetted fuel film on a flat wall inside a constant volume vessel. In the experiments, iso-octane mixed with biacetyl as a tracer dopant was injected through a pintle type injector against a flat glass wall under the ambient conditions of atmospheric pressure and room temperature. The thickness of the adhered fuel film on the wall was quantitatively measured by using laser induced fluorescence (LIF) technique, which provides 2-D distribution information with high special resolution as a function of the injection duration, the impingement distance from the injector to the wall, and the impingement angle against the wall.

We propose a new concept on simultaneous reduction of NO and soot emissions in Diesel engine exhaust by use of the diesel fuel oil (n-Tridecane) with liquefied CO2 dissolved. The CO2 dissolved component is expected to undergo flash boiling or gas separation when being injected into the combustion chamber, and improve spray atomization and mixing process both of which are primary factors to govern soot formation. Further, the internal EGR effect caused by CO2 component injected with the fuel is expected for NO formation. In order to assess this concept, spray dynamics measurement was conducted in the constant volume vessel with a variation of ambient pressure and temperature. Further, combustion experiments were carried out by using a rapid compression and expansion machine. Here, characteristics of the evaporative mixed fuel spray were examined by shadowgraph photography.

Three-dimensional large eddy simulation (LES) has been conducted for a diesel spray flame using KIVALES which is LES version of KIVA code. Modified TAB model, velocity interpolation model and rigid sphere model are used to improve the prediction of the fuel-mixture process in the diesel spray. Combustion is simulated using the Eddy-Dissipation model. CIP method was incorporated into the KIVALES in order to suppress the numerical instability on the combustible flow. The formation of soot and NO was simulated using Hiroyasu model and KIVA original model. Three different grid resolutions were used to examine the grid dependency. The result shows that the LES approach with 0.5 mm grid size is able to resolve the instantaneous spray with the intermittency in the spray periphery, the axi-symmetric shape and meandering flow after the end of injection as shown in the experimental results.

In this study, a rapid compression and expansion machine(RCEM) with a pancake combustion chamber was designed to investigate fundamentally on the knocking phenomena in spark ignition(S.I) engines. This RCEM is intended to simulate combustion in an actual engine. The homogeneous pre-mixture of n-pentane and air was charged into a quiescent atmosphere of the chamber. Then, the combustion field become simpler in this machine than it in a real S.I. engine. Also, the combustion phenomena, that is a cylinder pressure history, the behavior of flame propagation and so on, with high reproducibility are realized in this machine. The phenomena caught in this experiment were so-called low speed knocking. And, this knocking characteristics such as a knock intensity and a knock mass fraction were revealed by the cylinder pressure analysis varying the charge pressure and the equivalence ratio of the mixture, a compression ratio and an ignition timing.

The CO2 gas dissolved fuel for the diesel combustion is effective to reduce the NOx emissions to achieve the internal EGR (Exhaust Gas Recirculation) effect by fuel. This method has supplied EGR gas to the fuel side instead of supply EGR gas to the intake gas side. The fuel has followed specific characteristics for the diesel combustion. When the fuel is injected into the chamber in low pressure, this CO2 gas is separated from the fuel spray. The distribution characteristics of the spray are improved and the improvement of the thermal efficiency by reduction heat loss in the combustion chamber wall, and reduce soot emissions by the lean combustion is expected. Furthermore, this CO2 gas decreases the flame temperature. Further, it is anticipated to reduce NOx emissions by the spray internal EGR effect.

We have proposed the application of EGR gas dissolved fuel which might improve spray atomization through effervescent atomization instead of high injection pressure. In this paper, the purpose is to evaluate the influence of the application of CO2 gas dissolved fuel on the combustion characteristics and emissions inside the single cylinder, direct injection diesel engine. As a result, by use of the fuel, smoke was reduced by about 50 to 70%. The amount of NOx was reduced at IMEP=0.3 MPa, but it was increased at IMEP=0.9 MPa.

In a high-speed DI diesel engine, fuel sprays impinge surely on a wall of a piston cavity. Then the phenomenon of the heat transfer between the impinged spray and the wall appears and it has the strong effect on the combustion processes of the engine. The purpose of this study are to clarify basically the heat transfer characteristics. In the experiments, the fuel was injected into the quiescent inert atmosphere with a high temperature under high pressure field, and an evaporative single diesel spray was impinging upon a flat wall. And, the temperature distribution on the wall surface in a radial direction was detected by the Loex-Constantan thin film thermo-couples. Thus, the heat flux between the impinged spray and the wall surface was calculated from the temperature profile within the wall by Fourier's equation using the finite difference method, under the assumption of the one-dimensional heat conduction.

In the actual spray combustion fields, coupled combustion process should be occurred, between the pre-evaporate fuel component and remaining liquid droplets. Therefore it is insufficient to clarify the fundamental spray combustion mechanism with use of only droplet or only premixed mixture analyze method. In this study, the premixed mixture - droplets coupled combustion field was focused as a model of the actual spray combustion field. In the experiments, the effect of the flame pattern and the combustion rate constant by the interference between the droplets were clarified with the variation of fuels used by droplets. Besides, the effect of the premixed gas surrounding the droplets was clarified by the experiment on coupled combustion. The experiments were carried out under the normal gravity field and the micro gravity field to estimate the effect of convection in combustion field

It is significant for understanding the phenomena in a stratified charge engine and an SI engine with direct injection system to carry out the fundamental research. The experiments were conducted in a constant volume chamber with atmospheric condition. The pre-mixed charge composed of ethylene and air was charged with various equivalence ratio, the second charge with the same composition was injected into the chamber, thereafter, the combustion started by a spark plug. The phenomena were analyzed by use of the experimental results of shadowgraph, [OH] natural emission, pressure history and NOx and UHC in the exhaust gas.

In this study, the novel fuel design concept has been proposed in order to realize the low emission and combustion control in engine systems. In this fuel design concept, the mixed fuels with a high volatility fuel (gasoline or gaseous fuel components) and a low volatility fuel (gas oil or fuel oil components) are used in order to improve the spray characteristics by flash boiling. In our previous papers on this study, the fundamental characteristics of spray and its combustion of mixed fuel were reported. In this paper, heat release and exhaust emission (smoke, NOx and THC) characteristics of single cylinder diesel engine operated with the mixed fuels were investigated under each load. The exhaust performance of diesel engine could be improved using mixed fuel, because fuel properties and spray characteristics were controlled by changing mixing fraction of the mixed fuel.

In the present study, we have proposed a novel fuel design concept in order to achieve low emissions and combustion control in engine systems. The fuel design concept is based on the combustion control that could be realized by using a mixed fuel with a lower boiling point fuel, such as gasoline or gaseous fuel components and a higher boiling point fuel, such as gas oil or fuel oil components. According to the fuel design concept proposed in this work, the characteristics of vaporization during mixture formation process as well as of combustion can be reasonably improved due to the formation of two-phase region. The heat release analysis was conducted to compare the temporal history of heat release for both a mixed fuel and a single component fuel that has the same transport properties of mixed fuels. In addition, the two-color method, which simultaneously allows the measurements of temperature distribution and soot concentration, is applied to the combustion field for mixed fuels.

In previous our work, we revealed that the flash boiling process could improve remarkably the spray atomization for the pure substance-single component fuel in relation to the port-injected S.I. engines. Then, we applied this flash boiling spray to the Diesel spray process by the use of the two phase region formed between liquefied CO2 and n-Tridecane as the first step of fuel design concept. And the promoted atomization properties could be obtained in this mixed fuel concept. Further, we could obtain the simultaneous reduction of NO and soot emissions in Diesel engine exhaust due to the spray internal EGR effect and reburning of soot. As the second step, we proposed a novel fuel design concept for low exhaust emission and combustion control, relating to mixed and reformulated fuels with a lower boiling point fuel such as gasoline components or gas fuel and a higher boiling point fuel such as gas oil or heavy oil components to obtain the both advantages of their fuels for combustion.